Influence of ligands and anions on the insertion of alkenes into palladium-acyl and palladium-carbomethoxy bonds in the neutral complex (dppp)Pd(C(O)CH3)Cl and the ionic complexes [(PP)PdR(L)]+SO3CF3− (PP = dppe, dppp, dppb; R C(O)CH3, L CH3CN, PPh3; R C(O)OCH3, L PPh3)
- 16 June 1992
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 430 (3), 357-372
- https://doi.org/10.1016/0022-328x(92)83271-i
Abstract
No abstract availableKeywords
This publication has 70 references indexed in Scilit:
- Influence of ligands and anions on the rate of carbon monoxide insertion into palladium-methyl bonds in the complexes (P-P)Pd(CH3)Cl and [(P-P)Pd(CH3)(L)]+SO3CF3- (P-P = dppe, dppp, dppb, dppf; L = CH3CN, PPh3)Organometallics, 1992
- Efficient palladium catalysts for the copolymerization of carbon monoxide with olefins to produce perfectly alternating polyketonesJournal of Organometallic Chemistry, 1991
- Determination of key intermediates for homogeneous water-gas shift reaction and hydrocarbonylation of ethylene to diethyl ketone catalyzed by the ‘Pd(OAc)2-PPh3-CF3COOH/H2O’ systemJournal of Molecular Catalysis, 1989
- Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivativesJournal of the American Chemical Society, 1985
- Mechanism of acetylene and olefin insertion into palladium-carbon .sigma. bondsJournal of the American Chemical Society, 1984
- Transition metal catalyzed copolymerization of carbon monoxide with olefins. 2. Palladium(II)-catalyzed copolymerization of carbon monoxide with ethylene. Direct evidence for a single mode of chain growthOrganometallics, 1984
- Mechanism of transition-metal-catalyzed double carbonylation reactions. Synthesis and reactivity of benzoylformyl complexes of palladium(II) and platinum(II)Journal of the American Chemical Society, 1984
- New catalyst for the synthesis of dialkyl ketones from olefins, carbon monoxide, and hydrogenJournal of the Chemical Society, Chemical Communications, 1984
- The olefin insertion reactionJournal of the American Chemical Society, 1978
- Alternating oligomerization of ethylene and carbon monoxide catalyzed by rhodium carbonylTetrahedron Letters, 1971