Enantioselective synthesis of (R)- or (S)-2-alkylglutaraldehydic acid methyl esters via chiral organotin enamines

1 January 1985

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 8,p. 504-505
https://doi.org/10.1039/c39850000504

Abstract

Nucleophilic addition of chiral organotin enamines to electrophilic alkenes is described; a minor modification of experimental conditions gave the other enantiomer of 2-alkylglutaraldehydic acid methyl esters.

Keywords

CHIRAL ORGANOTIN
ORGANOTIN ENAMINES
ALKYLGLUTARALDEHYDIC ACID METHYL
ACID METHYL ESTERS
NUCLEOPHILIC
MINOR
EXPERIMENTAL

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