Comment on: ‘‘Predissociation of the d 1Πg Rydberg state in O2: Nature of the Rydberg–valence interactions’’
- 15 June 1989
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 90 (12), 7606-7607
- https://doi.org/10.1063/1.456196
Abstract
The rotational constants of the lowest vibrational levels of the d 1Πg state of O2 display an anomalous behavior which has been attributed to interactions between the Rydberg and valence 1Πg states. We confirm the suggestion by carrying out a theoretical analysis in which we solved numerically the pair of coupled equations that describe the interacting states.Keywords
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