Time resolved study of the uv and near uv continuums of xenon

Abstract

The spectroscopic analysis of xenon at pressures between 50 and 700 torr shows the presence of several continuums over a wavelength range of 110–700 nm. The kinetics of two of them, 173 and 210 nm, are studied. In both cases, the shape of the light pulse, reconstituted by a time‐amplitude conversion method, is defined by a difference of two exponential terms. These terms represent the formation and the decay of the molecular species. The variation of the time constants with pressure allows the reaction constants of the various processes in the kinetic scheme to be found. The continuum in the vuv is brought about by the ³Σ⁺_u state formed by three‐body collisions: k= (8.0±0.7)10⁻³² cm⁶ s⁻¹ and the lifetime τ=102±2 ns; in the near uv, the molecular state has a shorter lifetime τ′₁=8.2±0.5 ns but is formed like the previous one by three‐body collisions: k₃= (2.3±0.06)10⁻³⁰ cm⁶ s⁻¹. The near uv xenon emission constants ave very close to those we previously reported for argon and krypton.