Calculation of the Effect of Non-Brownian Motion on Some dc Transport Coefficients in Solution

Abstract

Effects of non‐Brownian motion on transport coefficients are found on the basis of a model in which the carrier undergoes random changes of state between two states of different mobility. The transport properties investigated are the electrical mobility, the Hall mobility, and the Onsager slope of the equivalent conductance. On the basis of these examples the relations among certain transport coefficients may be expected to be quite sensitive to the microscopic dynamics of the carrier.