Über die Reaktion von Hepten‐(3) und Allylcyanid in Gegenwart von CoO/MoO3/Al2O3‐ und WO3/SiO2‐Katalysatoren
- 1 January 1978
- journal article
- research article
- Published by Wiley in Journal für Praktische Chemie
- Vol. 320 (2), 177-182
- https://doi.org/10.1002/prac.19783200202
Abstract
Reaction of Hepten‐(3) and Allyl Cyanide with CoO/MoO3/Al2O3 and WO3/SiO2 CatalystsThe influence of the β nitrilgroup in allylcyanid was determined by comparison of the activity of hepten‐(3) and allylcyanid.Hepten‐(3) give with CoO/MoO3/Al2O3 and WO3/SiO2 catalysts mainly methathesis which is never observed with allylcyanid. This product gives only isomerisation in crotonitril and finally dimerisation – trimerisation of this last.This publication has 7 references indexed in Scilit:
- Olefin DisproportionationCatalysis Reviews, 1970
- The CoO$z.sbnd;MoO3$z.sbnd;Al2O3 catalyst II. The structure of the catalystJournal of Catalysis, 1969
- The mechanism of olefin disproportionationJournal of Catalysis, 1969
- Diene disproportionation reactionsJournal of Catalysis, 1969
- Tungsten Oxide on Silica Catalyst for Phillips' Triolefin ProcessI&EC Product Research and Development, 1968
- Olefin Disproportionation. A New Catalytic ProcessI&EC Product Research and Development, 1964
- 54. The chemistry of the three-carbon system. Part XXVIII. Nitriles of butenoic and hexenoic acids. A note on the analysis of unsaturated nitriles by halogen additionJournal of the Chemical Society, 1932