Chiral Olefins as Steering Ligands in Asymmetric Catalysis
Top Cited Papers
- 27 May 2008
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 47 (24), 4482-4502
- https://doi.org/10.1002/anie.200703612
Abstract
Metal-catalyzed asymmetric processes offer one of the most straightforward ways to introduce stereogenic centers. Hence, the development of novel chiral ligands that can effectively induce asymmetry in reactions is crucial in modern organic synthesis. While many established chiral ligands bind to a metal through heteroatoms, structures that coordinate to metals through carbon atoms have received little attention so far. Here, we highlight the increasing number of such chiral chelating olefin ligands as well as their application in a variety of metal-catalyzed transformations.Keywords
This publication has 186 references indexed in Scilit:
- Enantioselective Copper‐Catalyzed Conjugate Addition to Trisubstituted Cyclohexenones: Construction of Stereogenic Quaternary CentersAngewandte Chemie International Edition, 2005
- Rhodiumkatalysierte Addition von Organoboronsäuren an AldehydeAngewandte Chemie, 1998
- Ab initio calculations on (H3P)2Pt(C2H4). The effect of alkene pyramidalization on internal rotation and alkene binding energiesJournal of the American Chemical Society, 1991
- Organo (dipyridyl) nickel complexes. I. Stability and activation of the alkyl-nickel bonds of dialkyl (dipyridyl) nickel by coordination with various substituted olefinsJournal of the American Chemical Society, 1971
- Olefin coordination compounds of rhodium. V. Relative stabilities and rates of exchange of olefin complexes of rhodium(I)Journal of the American Chemical Society, 1967
- Cyclic Polyolefins. XLVI. Synthesis of 1,2-Di(hydroxymethyl)cyclooctatetraene and Cyclooctatetraene-1,2-dicarboxylic AcidJournal of the American Chemical Society, 1967
- Ring Inversion and Bond Shift in Cyclooctatetraene DerivativesJournal of the American Chemical Society, 1964
- Molecular Asymmetry of Olefins. I. Resolution of trans-Cyclooctene1-3Journal of the American Chemical Society, 1963
- The Rate of Bond Change in CycloöctatetraeneJournal of the American Chemical Society, 1962
- Cyclic Polyolefins. XXVII. cis- and trans-Cycloöctene from N,N-Dimethylcycloöctylamine1Journal of the American Chemical Society, 1953