ORGANIC DEUTERIUM COMPOUNDS: XIX. SYNTHESIS OF SOME DEUTERATED LAURIC ACIDS AND THEIR METHYL ESTERS
- 1 March 1958
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 36 (3), 440-448
- https://doi.org/10.1139/v58-063
Abstract
The synthesis of lauric acids deuterated in the carboxyl, the terminal methyl, and the α-methylene groups and in various combinations of these is described. The methyl and methyl-d3 esters of each of the acids were also prepared.Two further examples of homolytic halide addition to olefins are reported.The reaction between alkyl halides and silver acetylides is described. A mechanism involving a new type of free radical is postulated.Keywords
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