FAR INFRARED AND RAMAN SPECTRA AND STRUCTURE OF DITHIOPHOSGENE
- 1 September 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (9), 2107-2112
- https://doi.org/10.1139/v64-311
Abstract
The infrared spectrum in the range 3000–50 cm−1 and the Raman spectrum of solutions of dithiophosgene have been obtained. There are no coincidences in the infrared and Raman spectra, and the only structure consistent with this and approximately tetrahedral carbon valencies is that is tetrachloro-1,3-dithietane, in which the ring is planar or nearly planar. A tentative assignment of the observed bands is given on the basis of D2h symmetry.Keywords
This publication has 5 references indexed in Scilit:
- Far infrared absorption, vibrational spectra and structure of tetrafluoro-1,3-dithietaneSpectrochimica Acta, 1963
- Far Infrared Spectrum of Trimethylene OxideThe Journal of Chemical Physics, 1960
- The normal vibrations of bridgeX2Y6moleculesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1945
- Die Ramanspektren der flüssigen und festen Chlor-, Bromund Jodverbindungen des AluminiumsZeitschrift für Physikalische Chemie, 1941
- Thermodynamic functions and equilibria of formaldehyde, deuteroformaldehyde, phosgene and thiophosgeneTransactions of the Faraday Society, 1941