Mass Spectrometric Study of NF2, NF3, N2F2, and N2F4.
- 1 September 1961
- journal article
- Published by National Institute of Standards and Technology (NIST) in Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
- Vol. 65 (5), 405-409
- https://doi.org/10.6028/jres.065A.041
Abstract
Appearance potentia's have been measured for selected ions from NF2, NF3, N2F2, and N2F4. Ionization-dissociation processes are identified and bond dissociation energies are calculated. In addition, the bond dissociation energy, D(F2N-NF2), has been directly measured to be 5.14±0.38 kj/mole (21.5± 1.6 kcal/mole). A summary is made of available thermochemical and mass spectrometric data for N-F compounds and some evidence is presented to support the designation of cis and trans structures for the N2F2 isomers.Keywords
This publication has 1 reference indexed in Scilit:
- Absolute Rate Theory for Isolated Systems and the Mass Spectra of Polyatomic MoleculesProceedings of the National Academy of Sciences, 1952