Dynamics of Block Copolymer Micelles Revealed by X-Ray Intensity Fluctuation Spectroscopy

Abstract
We report x-ray intensity fluctuation spectroscopy measurements of the equilibrium dynamics of polymer micelle liquids, composed of polystyrene-polyisoprene block copolymer micelles within a polystyrene homopolymer matrix. The equilibrium dynamics were investigated for times between one and several hundred seconds, and for wave vectors from 0.003 to 0.0151, far beyond wave vectors that can be studied with visible light. A wave-vector-dependent diffusion coefficient is found.