Chiral (iminophosphoranyl)ferrocenes: highly efficient ligands for rhodium- and iridium-catalyzed enantioselective hydrogenation of unfunctionalized olefins
- 17 July 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 33,p. 3537-3539
- https://doi.org/10.1039/b607450b
Abstract
A series of chiral (iminophosphoranyl)ferrocenes (1–3) are highly efficient ligands for Rh- and Ir-catalyzed hydrogenation of a number of unfunctionalized olefins; almost perfect enantiomeric excesses (up to 99% ee) have been achieved under mild reaction conditions.Keywords
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