[Ni2O(l-Asp)(H2O)2]·4H2O: A Homochiral 1D Helical Chain Hybrid Compound with Extended Ni−O−Ni Bonding
- 25 February 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (10), 3044-3045
- https://doi.org/10.1021/ja031836f
Abstract
The hydrothermally synthesized 1D homochiral nickel aspartate oxide [Ni2O(l-Asp)(H2O)2]·4H2O is based on infinite helical chains of edge- and corner-sharing nickel octahedra. It represents the first example of a chiral one-dimensional compound with an extended helical TM−O−TM subnetwork synthesized as an optically pure product. Its structure was determined ab initio by real-space methods from laboratory powder diffraction data.Keywords
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