Kinetische Racematspaltung sekundärer Alkohole durch Ruthenium(II)‐katalysierte Transferhydrierung
- 3 February 1997
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 109 (3), 300-303
- https://doi.org/10.1002/ange.19971090334
Abstract
Mit Aceton als Wasserstoffacceptor gelingt unter RuII‐Katalyse die kinetische Racematspaltung sekundärer Alkohole. Diese Methode eröffnet einen Zugang zu Alkoholen, die nicht einfach durch enantioselektive Reduktion der entsprechenden Ketone erhältlich sind (Beispiele für Edukte rechts), und ist für meso‐Verbindungen von besonderem Interesse. R1 = (CH3)2N, R2 = H, CH3. magnified imageThis publication has 59 references indexed in Scilit:
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