Nuclear motion effects in the photoionisation of CO2
- 14 April 1980
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 13 (7), L231-L234
- https://doi.org/10.1088/0022-3700/13/7/002
Abstract
A calculation of the photoionisation cross section of CO2 reveals that the sigma u shape resonance at approximately 19 eV, accessed by the 1 pi g and 4 sigma g valence levels, is reduced and broadened by coupling to the ground-state vibrational motion. Off resonance the effect of nuclear motion is negligible. Results are compared with experimental branching ratios.Keywords
This publication has 11 references indexed in Scilit:
- Shape-Resonance-Enhanced Nuclear-Motion Effects in Molecular PhotoionizationPhysical Review Letters, 1979
- Energy dependence of the differential photoelectron cross sections of molecular nitrogenThe Journal of Chemical Physics, 1978
- Partial photoionization cross sections of Cbetween 20 and 40 eV studied with synchrotron radiationPhysical Review A, 1978
- Partial photoionization cross sections ofand CO using synchrotron radiationPhysical Review A, 1977
- Angular distribution of photoelectrons at 584 Å using polarized radiationJournal of Electron Spectroscopy and Related Phenomena, 1976
- Electron-molecule scattering and molecular photoionization using the multiple-scattering methodThe Journal of Chemical Physics, 1974
- Photoionization of the Noble Gases: Cross Sections and Angular DistributionsPhysical Review A, 1972
- Angular Distribution of the Photoelectron Spectra for Ar, Kr, Xe, H2, N2, and COThe Journal of Chemical Physics, 1971
- Angular dependence of vibrational structure in the photoelectron spectra of N2 and O2Chemical Physics Letters, 1971
- Adiabatic Approximation for Scattering ProcessesPhysical Review B, 1956