Absolute rate constants for hydrocarbon autoxidation. V. The hydroperoxy radical in chain propagation and termination
- 15 April 1967
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 45 (8), 785-792
- https://doi.org/10.1139/v67-131
Abstract
The hydroperoxy radical (HOO·) is the main chain propagating and terminating radical in the autoxidation of dilute solutions of 1,4-cyclohexadiene and 1,4-dihydronaphthalene in chlorobenzene at 30 °C. The absolute rate constant for the self-reaction of hydroperoxy radicals (chain termination) in nonpolar solvents is very much higher than previously reported values in aqueous media.Keywords
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