ROTATIONAL ANALYSIS OF BANDS OF THE HCF MOLECULE

Abstract

A new transient absorption spectrum, belonging to the HCF free radical, has been discovered in the flash photolysis of dibromofluoromethane, HCFBr2. The spectrum consists of a single progression of complex bands in the region 4 300–6 000 Å. Rotational analysis of the less severely perturbed bands shows them to be type-C bands of a molecule that is nonlinear in both upper and lower states of the transition, with bond angles of ~ 127° and ~ 102° respectively. Axis-switching effects, due to the large change of bond angle in the transition, cause the appearance of prominent gQ, qQ, and °Q branches, in addition to those obeying the ordinary type-C selection rules.The principal molecular constants of HCF (in cm−1) are:[Formula: see text]