Effects of Th doping on structural and superconductive properties of La2−xBaxCuO4

Abstract

The striking suppression of superconductivity of ${\mathrm{La}}_{2\mathrm{-}\mathit{x}}$ ${\mathrm{Ba}}_{\mathit{x}}$ ${\mathrm{CuO}}_4$ in a narrow range of x around 0.125 is known to be a consequence of a structural transition to a low-temperature tetragonal phase below about 60 K. Study of low-temperature lattice instabilities by x-ray diffraction revealed that in ${\mathrm{La}}_{2\mathrm{-}\mathit{y}\mathrm{-}\mathit{x}}$ ${\mathrm{Th}}_{\mathit{y}}$ ${\mathrm{Ba}}_{\mathit{x}}$ ${\mathrm{CuO}}_4$ the development of the low-temperature tetragonal phase, as well as the sharp suppression of superconductivity, is centered at x-y≃0.125, instead of x≃0.125. Therefore, the anomalous low-temperature behavior is essentially characterized by the density of carriers rather than local ionic forces, which couples with the lattice instabilities.