Silicone‐polyethylene blends

Abstract

Polyethylene and reactive, high molecular weight polydimethylsiloxanes have been blended under conditions of shear and elevated temperature in order to form uniform, thermoplastic blends. The materials can be extruded, coated on wire, injection molded, or compression molded. Despite the thermoplastic nature, a high gel fraction is present. A structure is proposed consisting of microgelled and grafted particles of silicone dispersed in polyethylene. When compared to pure polyethylene, the blends show lowered modulus over a temperature range of −150 to +65°C increased gas permeability, and lowered mixing energies. Electrical properties include corona resistance superior to polyethylene and a resistance to degradation under conditions simulating those experienced by buried cables superior to typical silicone rubber. Other electrical properties are intermediate between the values observed in the component polymers.