3d Wavefunctions in 57Fe Mössbauer Spectroscopy
- 1 November 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 55 (9), 4238-4245
- https://doi.org/10.1063/1.1676741
Abstract
In a remarkable article, Ganiel has shown that 57Fe quadrupole splitting due to a single 3d electron is constant, for any real wavefunction with real coefficients spanning either the T2g or Eg subspaces. We examine here the effects on Vzz and η and show that these vary in complex fashion. Hence, the sensitive effects of structure and bonding on the efg tensor can be buried in a constant quadrupole splitting for this case, and the values of Vzz and η must be extracted by magnetic perturbation or other methods if the nature of the 3d wavefunctions is to be determined.Keywords
This publication has 3 references indexed in Scilit:
- On the quadrupole splitting in ferrous compoundsChemical Physics Letters, 1969
- The Perspective Representation of Functions of Two VariablesJournal of the ACM, 1968
- CONTRIBUTED PAPERS FOR SESSION IReviews of Modern Physics, 1964