Simulated light-scattering experiments on liquid chlorine

Abstract

Different potential models are exploited for deriving the allowed and induced Raman spectra of liquid chlorine at T = 200 K and ρ = 1·414 × 10²⁸ m^-3. The induced effects are evaluated within the DID (dipole-induced-dipole) scattering mechanism in the point-scatterers approximation. The time correlation functions of allowed and induced polarizabilities, the depolarization ratios, the isotropic and anisotropic spectral shapes and the second spectral moments have been computed for the different potential models and compared with the available experimental data.