Notizen: Zinnorganische Fluoride als Fluorierungsreagenzien für Chloride von Hauptgruppenelementen - Quantitatives Recycling des Fluorierungsreagenzes / Tinorganic Fluorides Function as Fluorinating Reagents for Chlorides of Main Group Elements - Quantitative Recycling of the Fluorinating Reagent

Abstract

PF₃ is obtained in high purity by reacting PCl₃ with Me₃SnF. Alternative fluorinating reagents for this reaction are Ph₃SnF and (i-C₄H₉)₃SnF. The reaction with the isobutyl derivative is less complicated since the resulting chloride is a liquid in contrast to Ph₃SnCl being a solid. PCl₅, MeCOCl, SiCl₄, Me₃SiCl, and SOCl₂ react with Me₃SnF to give also the corresponding fluorides. The resulting chlorides are easily converted again to the fluorides. A quantitative recycling of the fluorinating reagent is therefore achieved.