The Electrostatic Influence of Substituents on the Dissociation Constants of Organic Acids. II
- 1 September 1938
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 6 (9), 513-517
- https://doi.org/10.1063/1.1750303
Abstract
The theory of the influence of substituents on dissociation constants presented in an earlier article of the same title is extended to acids ellipsoidal in shape. Bjerrum's formula is obtained in the limiting case of unit eccentricity of the elliptical section of a prolate ellipsoid of revolution. The influence of dipolar as well as ionic substituents can satisfactorily be treated.This publication has 2 references indexed in Scilit:
- The Electrostatic Influence of Substituents on the Dissociation Constants of Organic Acids. IThe Journal of Chemical Physics, 1938
- Gesetzmäßigkeiten für die Veränderlichkeit der Affinitätskonstanten substituierter organischer SäurenAngewandte Chemie, 1932