Catalytic Asymmetric Olefin Metathesis
Top Cited Papers
- 23 February 2001
- journal article
- concept
- Published by Wiley in Chemistry – A European Journal
- Vol. 7 (5), 945-950
- https://doi.org/10.1002/1521-3765(20010302)7:5<945::aid-chem945>3.0.co;2-3
Abstract
This paper provides a survey of the first examples of efficient catalytic enantioselective olefin metathesis reactions. Mo‐catalyzed asymmetric ring‐closing (ARCM) and ring‐opening (AROM) reactions allow access to myriad optically enriched compounds that are otherwise difficult to access.Keywords
This publication has 39 references indexed in Scilit:
- Sequential Intramolecular Cyclobutadiene Cycloaddition, Ring-Opening Metathesis, and Cope Rearrangement: Total Syntheses of (+)- and (−)-AsteriscanolideJournal of the American Chemical Society, 2000
- Assembly of (−)-Cylindrocyclophanes A and F via Remarkable Olefin Metathesis DimerizationsJournal of the American Chemical Society, 2000
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Cross MetathesisJournal of the American Chemical Society, 1999
- Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing MetathesisJournal of the American Chemical Society, 1998
- Chromenes through Metal-Catalyzed Reactions of Styrenyl Ethers. Mechanism and Utility in SynthesisJournal of the American Chemical Society, 1998
- Selective Ring-Opening Olefin Metathesis of Functionalized Monosubstituted OlefinsAngewandte Chemie International Edition in English, 1997
- Ru-Catalyzed Rearrangement of Styrenyl Ethers. Enantioselective Synthesis of Chromenes through Zr- and Ru-Catalyzed ProcessesJournal of the American Chemical Society, 1997
- Ring Opening Metathesis Polymerization with Binaphtholate or Biphenolate Complexes of MolybdenumMacromolecules, 1996
- Asymmetric Ring-Closing Metathesis: Kinetic Resolution Catalyzed by a Chiral Molybdenum Alkylidene ComplexJournal of the American Chemical Society, 1996
- Synthesis of chiral molybdenum ROMP initiators and all-cis highly tactic poly(2,3-(R)2norbornadiene) (R = CF3 or CO2Me)Journal of the American Chemical Society, 1993