Stereocontrolled synthesis of highly oxygenated acyclic systems via the enolate Claisen rearrangement of O-protected allylic glycolates
- 1 August 1987
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 52 (17), 3889-3901
- https://doi.org/10.1021/jo00226a032
Abstract
No abstract availableThis publication has 13 references indexed in Scilit:
- Asymmetric reductions of .alpha.,.beta.-acetylenic ketones and acetophenone using lithium aluminum hydride complexed with optically active 1,3-amino alcoholsThe Journal of Organic Chemistry, 1980
- Enolate Claisen rearrangement of esters from furanoid and pyranoid glycalsThe Journal of Organic Chemistry, 1980
- Synthesis of (2R,4'R,8'R)-.alpha.-tocopheryl acetate (vitamin E acetate) using [3,3] sigmatropic rearrangementThe Journal of Organic Chemistry, 1978
- Total synthesis of (.+-.)-sarraceninThe Journal of Organic Chemistry, 1978
- Transfer of chirality in the [2,3] sigmatropic rearrangement of allylic alcohols to .beta.,.gamma.-unsaturated amides. Preparation of optically active nine- and fourteen-carbon saturated isoprenoid synthonsThe Journal of Organic Chemistry, 1977
- Absolute configuration of (−)-4-methylheptan-3-ol, a pheromone of the smaller european elm bark beetle, as determined by the synthesis of its (3R,4R)-(+)- and (3S,4R)-(+)-isomersTetrahedron, 1977
- Synthetic studies on (2R,4'R,8'R)-.alpha.-tocopherol. An approach utilizing side chain synthons of microbiological originThe Journal of Organic Chemistry, 1976
- Synthetic studies on (2R,4'R,8'R)-.alpha.-tocopherol. An alternative synthesis of (2R,6R)-(+)-2,6,10-trimethylundecan-1-ol, a key side chain synthonThe Journal of Organic Chemistry, 1976
- Synthetic studies on (2R,4'R,8'R)-.alpha.-tocopherol. Facile syntheses of optically active, saturated, acyclic isoprenoids via stereospecific [3,3] sigmatropic rearrangementsThe Journal of Organic Chemistry, 1976
- Sex Pheromone Specificity in the Pine Sawflies: Interchange of Acid Moieties in an EsterScience, 1976