Turbulent flow drag reduction and degradation with dilute polymer solutions

Abstract

Experimental studies of drag reduction and polymer degradation in turbulent pipe flow with dilute water solutions of unfractionated polyethylene oxide are described. Drag reduction results indicate that the magnitude of the reduction cannot be correlated on the basis of weight average molecular weight, rather the phenomenon depends strongly on the concentration of the highest molecular weight species present in the molecular weight distribution. Polymer degradation in turbulent flow is found to be severe for high molecular weight polymers causing appreciable changes in drag reduction and molecular weight with the duration of flow. Data indicates that drag reduction exists in the limit of infinite dilution suggesting that the phenomenon is due to the interaction of individual polymer molecules with the surrounding solvent and that the extent of reduction is relatively independent of pipe diameter when a comparison is carried out at equal solvent wall shear stresses. Consideration of the high viscosity obtained with solutions in an irrotational laminar flow field suggests this is due to polymer molecule deformation and that this phenomenon is central to the mechanism of turbulent flow drag reduction.