Controlling Photochemistry with Distinct Hydrophobic Nanoenvironments
- 20 October 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (44), 14366-14367
- https://doi.org/10.1021/ja0450197
Abstract
A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity.Keywords
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