THE THERMAL DECOMPOSITION OF HEXAFLUOROAZOMETHANE
- 1 May 1962
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 40 (5), 930-934
- https://doi.org/10.1139/v62-139
Abstract
The pyrolysis of hexafluoroazomethane has been studied in a static system between 0.3 mm and 73 mm and 572 °K and 634 °K by measuring the rate of nitrogen formation. The rate constant of the high-pressure homogeneous reaction is given by k = 1016.17±0.15 exp (−55,200 ± 400/RT) sec−1Keywords
This publication has 4 references indexed in Scilit:
- High Frequency Factors in Unimolecular ReactionsThe Journal of Chemical Physics, 1961
- The Thermal Decomposition of 2,2'-Azoisobutane1Journal of the American Chemical Society, 1960
- Photolysis of HexafluoroazomethaneThe Journal of Chemical Physics, 1955
- THE DECOMPOSITION OF AZO-ISOPROPANE. A HOMOGENEOUS UNIMOLECULAR REACTIONJournal of the American Chemical Society, 1928