Mass Spectral Studies of Kinetics behind Shock Waves. I. Thermal Dissociation of Chlorine
- 1 November 1963
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 39 (9), 2115-2120
- https://doi.org/10.1063/1.1701410
Abstract
The coupling of a shock tube to a time‐of‐flight mass spectrometer for the determination of kinetic data is described whereby analysis is performed every 25 μsec. The rate of dissociation of Cl2 has been measured over the temperature range 1700°—3200°K under essentially isothermal and isobaric conditions with the observed rate constants in fair agreement with those obtained by the spectroscopic technique. The observed temperature dependence is less than predicted by simple collision theory with an apparent activation energy of 41±5 kcal/mole.Keywords
This publication has 25 references indexed in Scilit:
- NON-EQUILIBRIUM EFFECTS IN THE DISSOCIATION OF DIATOMIC MOLECULES BY A THIRD BODY1The Journal of Physical Chemistry, 1963
- THE DISSOCIATION OF DIATOMIC MOLECULES AND THE RECOMBINATION OF ATOMSThe Journal of Physical Chemistry, 1962
- THE KINETICS OF DISSOCIATION OF A DIATOMIC GASThe Journal of Physical Chemistry, 1961
- O 2 Dissociation Rates O2-Ar MixturesThe Journal of Chemical Physics, 1961
- SHOCK WAVES IN CHEMICAL KINETICS: FURTHER STUDIES IN THE RATE OF DISSOCIATION OF BROMINEThe Journal of Physical Chemistry, 1960
- Shock wavesQuarterly Reviews, Chemical Society, 1960
- Theory of Thermal Second-Order Decomposition of MoleculesThe Journal of Chemical Physics, 1959
- Shock Tube studies on the Pyrolysis and Oxidation of MethaneThe Journal of Physical Chemistry, 1959
- A Mass Spectrometric Study of Flash Photochemical Reactions. IJournal of the American Chemical Society, 1957
- Vibrational relaxation in oxygen and nitrogenJournal of Fluid Mechanics, 1956