An Efficient Synthesis of Dihydrojasmone Utilizing a Cationic [(Propargyl)dicobalt Hexacarbonyl] Complex
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 10 (7), 503-507
- https://doi.org/10.1080/00397918008069325
Abstract
As part of a program to explore the organic chemistry of cobalt-stabilized propargyl cations 1, we recently found that these complexes readily and selectively α-alkylate ketones and ketone derivatives including TMS enol ethers and enol acetates2 (eq. 1).Keywords
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- Dihydrojasmone Synthesis. Pyrolytic Cleavage of a Cyclopropyl KetoneSynthetic Communications, 1977
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- A New Synthesis of 1,4- and 1,5-DiketonesJournal of the American Chemical Society, 1964