THE TRITYL PERCHLORATE CATALYZED MICHAEL REACTION
- 5 July 1985
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 14 (7), 953-956
- https://doi.org/10.1246/cl.1985.953
Abstract
In the presence of a catalytic amount of trityl perchlorate, 1,5-dicarbonyl compounds, the Michael adducts, are obtained in high yields by the reaction of silyl enol ethers with α,β-unsaturated ketones. The intermediate adducts, the synthetically valuable silyl enol ethers, are also isolated in high yields.Keywords
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