Thiophene C−H Activation as a Chain-Transfer Mechanism in Ethylene Polymerization: Catalytic Formation of Thienyl-Capped Polyethylene
- 1 June 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 121 (25), 6082-6083
- https://doi.org/10.1021/ja984288s
Abstract
No abstract availableThis publication has 16 references indexed in Scilit:
- Silanolytic Chain Transfer in Ziegler−Natta Catalysis. Organotitanium-Mediated Formation of New Silapolyolefins and Polyolefin ArchitecturesJournal of the American Chemical Society, 1998
- Metalation as a Termination Step in Polymerization Reactions Involving α-Olefins and Ethylene As Detected by Field Desorption Mass Spectrometry1Organometallics, 1996
- Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane CatalystsMacromolecules, 1996
- Silanes as Chain Transfer Agents in Metallocene-Mediated Olefin Polymerization. Facile in Situ Catalytic Synthesis of Silyl-Terminated PolyolefinsJournal of the American Chemical Society, 1995
- Activation of Ethers and Sulfides by Organolanthanide Hydrides. Molecular Structures of (Cp*2Y)2(.mu.-OCH2CH2O)(THF)2 and (Cp*2Ce)2(.mu.-O)(THF)2Organometallics, 1995
- Carbon-hydrogen activation of arenes and substituted arenes by the yttrium hydride (Cp*2YH)2: competition between Cp* ligand metalation, arene metalation, and hydrogen/deuterium exchange. Molecular structures of Cp*2Y(.mu.-H)(.mu.-.eta.1,.eta.5-CH2C5Me4)YCp* and Cp*2Y(o-C6H4PPh2CH2)Organometallics, 1993
- Ring hydrogen C-H activation in Cp*2LnCH(SiMe3)2 (Ln = yttrium, lanthanum, cerium): x-ray crystal structures of [Cp*3(.mu.3-.eta.5,.eta.1,.eta.1-C5Me3(CH2)2)Ce2]2 and Cp*2CeCH2C6H5Organometallics, 1991
- Zirconium-catalyzed coupling of propene and .alpha.-picolineJournal of the American Chemical Society, 1989
- .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bondsJournal of the American Chemical Society, 1987
- Facile C–H activation by lutetium–methyl and lutetium–hydride complexesJournal of the Chemical Society, Chemical Communications, 1983