Osmium nitrido-complexes with triphenyl-phosphine, -arsine, and -stibine, with evidence for nitrene-like behaviour of the phosphine complex

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Abstract
The new complexes [OsNX3(AsPh3)2] and [OsNCl3(LPh3)2](X = Cl or Br, L = P or Sb) have been made; we propose that nucleophilic attack of the nitrogen atom by triphenylphosphine occurs in some of these complexes to give derivatives of triphenylphosphine imine.