Expedient and High-Yield Synthesis of Alkylphos-Phonyl Bichlorides Under Mild, Neutral Conditions: Reaction of Bis(Trimethylsilyl)Alkyl Phosphonates with Oxalyl Chloride/Dimethylformamide
- 1 June 1987
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 17 (9), 1071-1076
- https://doi.org/10.1080/00397918708078788
Abstract
Structurally variant bis(trimethylsilyl)alkyl phosphonates were converted in high yields (80–88%, distilled) to the corresponding phosphonyl dichlor-ides upon reaction with (COCl)2/DMF.Keywords
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