Perturbation Theory for Repulsive Forces in Classical Fluids: Selected Applications
- 15 May 1972
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 56 (10), 4989-4994
- https://doi.org/10.1063/1.1676979
Abstract
The ``blip function'' expansion is a method for describing the equilibrium structure and thermodynamics of repulsive force systems in terms of properties of a hard sphere fluid. In this paper, the expansion is generalized to apply to multicomponent systems in which the intermolecular forces are angular dependent. Several applications are presented which illustrate the usefulness and the limitations of the theory.Keywords
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