Abstract
All experiments on the velocity with which different gases rush into a vacuum, or pass under pressure through an aperture in a thin plate, are in strict accordance with the physical law that the times of passage for equal volumes are proportional to the square roots of the densities of the various gases. Besides being the law of “Effusion,” this is also the law of the Diffusion of one gas into an atmosphere of another gas. The result in both cases is simply and exclusively a consequence of specific gravity. The velocity with which gases of different nature pass through a tube is necessarily much influenced by the law of their effusion, when the tube is short and approaches in character to an aperture in a thin plate. But if the length of the tube is progressively increased, its diameter or the aperture remaining constant, then while the resistance increases and the passage for all gases becomes greatly slower, the velocities of the different gases are found rapidly to diverge from those of their effusion. The velocities of different gases appear at last however to attain a particular ratio with a certain length of tube and resistance; and preserve the same relation to each other for greater lengths and resistances. After attaining this constant ratio, the passage of all the gases becomes slower, exactly in proportion to the increased length of the tube, that is, in proportion to the resistance. The different gases are now equally affected by the resistance, and their relative velocities are therefore undisturbed and remain constant. The effect of the law of effusion upon the velocities is no longer sensible, and appears to be eliminated.