Solid State Solvation in Amorphous Organic Thin Films

Abstract

The photoluminescence (PL) of the red laser dye DCM2, doped into blended thin films of polystyrene (PS) and the polar small molecule camphoric anhydride (CA), redshifts as the CA concentration increases. The DCM2 PL peaks at 2.20 eV ($\lambda =563\mathrm{n}\mathrm{m}$) for pure PS films and shifts to 2.05 eV ($\lambda =605\mathrm{n}\mathrm{m}$) for films with 24.5% CA (by mass). The capacitively measured electronic permittivity also increases from $ϵ=2.4$ to $ϵ=5.6$ with CA concentration. These results are consistent with the theory of solvatochromism developed for organic molecules in liquid solvents. To our knowledge, this work is the first application of a quantitative theory of solvation to organic molecules in amorphous thin films with continuously controllable permittivity, and demonstrates that “solid state solvation” can be used to predictably tune exciton energies in organic thin film structures.