Abstract
A beam of monoenergetic positrons incident on clean metallic surfaces has been employed to measure positronium yield as a function of sample temperature and positron energy. These results show an increase in the positronium fraction as a function of temperature which is identified as thermally activated detrapping of positrons from a surface trap. Estimates are made of the depths of these traps. Positrons are observed to trap at vacancies and a monovacancy formation enthalpy is extracted from the data utilizing a simple model.