Chiral recognition in the reaction of the enolate derived from [(η5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph] with 1-phenylethyl bromide
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 797-799
- https://doi.org/10.1039/c39900000797
Abstract
Chiral recognition to the extent of 30 : 1 has been observed in the reaction between the homochiral iron acyl complex [(η5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph] and racemic 1-phenylethyl bromide.Keywords
This publication has 10 references indexed in Scilit:
- Diastereoselective alkylation guided by electrophile-nucleophile .pi.-interactionsThe Journal of Organic Chemistry, 1988
- An approach to the stereoselective synthesis of α-hydroxycarboxylic acidsJournal of Organometallic Chemistry, 1987
- Alkylation stereochemistry of camphor derivatives of glycinates. Double chiral induction with secondary halides.Tetrahedron Letters, 1986
- Chiral discrimination in the reactions of the enolate E-[(η5-C5H5)Fe(CO)(PPh3)COCHMe]−Li+ withTetrahedron Letters, 1985
- Chiral discrimination in the reaction of the enolate [(η5-C5H5)Fe(CO)(PPh3)(COCH2)]–Li+with monosubstituted epoxides: X-ray crystal structure of (RS,SR)-[(η5-C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}]Journal of the Chemical Society, Chemical Communications, 1985
- Metal-assisted cycloadditions. Part 3. Reactions of dicarbonyl(η5-cyclopentadienyl)(η1-2-methoxyallyl)iron with electron-deficient olefins and acetylenesJournal of the Chemical Society, Perkin Transactions 1, 1982
- Transition-metal peroxide reactions. Synthesis of .alpha.-hydroxycarbonyl compounds from enolatesThe Journal of Organic Chemistry, 1978
- Nuclear magnetic resonance determination of enantiomeric composition and absolute configuration of .gamma.-lactones using chiral 2,2,2-trifluoro-1-(9-anthryl)ethanolThe Journal of Organic Chemistry, 1977
- Oxazolines. XXI. Kinetic resolution of sec-alkyl halides and simultaneous asymmetric synthesis of 3-alkylalkanoic acids using a chiral oxazoline. A method for determining absolute configurations and maximum optical rotationsJournal of the American Chemical Society, 1976
- 250. Aliphatic substitution and the Walden inversion. Part IIJournal of the Chemical Society, 1936