The Platinum Catalyzed Reduction of Nitroarenes to Aminoarenes with Carbon Monoxide and Water
- 1 October 1984
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 57 (10), 2867-2870
- https://doi.org/10.1246/bcsj.57.2867
Abstract
Nitroarenes were transformed into the corresponding aminoarenes in high yields at 80 °C with carbon monoxide (an initial pressure 30–60 kg cm−2) and water in the presence of a catalytic amount of a platinum catalyst. The platinum catalyst was combined with tin(IV) chloride, triphenylphosphine and triethylarnine. This combination was essential for the high catalytic activity.Keywords
This publication has 18 references indexed in Scilit:
- The platinum catalyzed reduction of nitroarenes to aminoarenes with carbon monoxide and waterTetrahedron Letters, 1983
- Facile reduction of nitrobenzene using carbon monoxide and water catalyzed by rhodium carbonyl cluster-amine systemsJournal of Molecular Catalysis, 1981
- The ruthenium carbonyl catalyzed reduction of nitro compounds by phase transfer catalysisTetrahedron Letters, 1980
- Olefin Hydrogenation by carbon monoxide and water using a platinum chloride-tin chloride catalyst systemJournal of Organometallic Chemistry, 1980
- Metal cluster catalysis. 2. Selective reduction of nitrobenzene catalyzed by rhodium carbonyl cluster anions. Evidence for water gas shift reactionJournal of Molecular Catalysis, 1979
- Homogeneous catalysis of the water gas shift reaction using a platinum chloride-tin chloride systemJournal of the American Chemical Society, 1978
- Activation of water molecule. 1. Intermediates bearing on the water gas shift reaction catalyzed by platinum(0) complexesJournal of the American Chemical Society, 1978
- Catalytic reductions using carbon monoxide and water in place of hydrogen. 2. Reduction of aromatic nitro compounds to aminesJournal of the American Chemical Society, 1978
- Die übergangsmetall‐katalysierte reduktive Carbonylierung von Arylaziden zu 1,3‐DiarylharnstoffenHelvetica Chimica Acta, 1972
- Catalytic deoxygenation of organic compounds by carbon monoxide. II. Direct synthesis of Schiff bases from aromatic nitro derivatives, aldehydes, and carbon monoxideThe Journal of Organic Chemistry, 1972