Piezoelectricity-induced terahertz photon absorption by confined acoustic phonons in wurtzite CdSe nanocrystals

Abstract

We report here the observation of piezoelectricity-induced terahertz photon absorption related to confined acoustic phonons in nanoparticles. Terahertz photon inactive $(l=0)$ breathing modes become terahertz photon active in wurtzite CdSe nanocrystals due to the piezoelectric coupling. Obvious absorption peaks related to $(l=0)$ modes appeared in the terahertz absorption spectra and the frequency of the peaks were inversely proportional to the size of the CdSe nanocrystals. This piezoelectrically coupled electric vibration provides a mechanism for low-dimensional systems to convert a terahertz photon into a phonon of the same frequency.