Absolute quantum efficiencies

Abstract

Recent developments in several areas of chemistry, laser technology, photodetector instrumentation, and calorimetry are surveyed, and their probable impact on the measurement of quantum yields is assessed. Chemical developments include: (a) synthesis and design of new luminescent molecules that could possibly serve as standards, (b) application of improved separation techniques to provide samples of extreme purity, and (c) advances in photochemistry that portend the development of wide-range chemical actinometers. The potential use of lasers in quantum-yield measurements and their advantages over conventional sources for application in both optical and calorimetric techniques are pointed out. New methods of quantum-yield measurements, based on the novel characteristics of laser pump sources, are suggested, including the feasibility of measuring yields under time-resolved conditions and of employing internal standards. The possible lifting of wavelength restrictions on both laser sources and detector devices and the implications of these developments for extending the spectral range of quantum-yield measurements are discussed. The current status of calorimetry for determining yields is surveyed, and the impact of recent technology on the feasibility of developing calorimetric methods competitive with optical methods is assessed.