Studies of Hydrogen Vibrations in Transition Metal Hydrides by Thermal Neutron Transmissions
- 1 October 1964
- journal article
- research article
- Published by Physical Society of Japan in Journal of the Physics Society Japan
- Vol. 19 (10), 1862-1866
- https://doi.org/10.1143/jpsj.19.1862
Abstract
The total scattering cross sections of hydrogen atoms for thermal neutrons were measured as a function of the neutron energy for TiH 1.3 , TiH 1.6 , TiH 1.9 , TiH 2.0 , VH 0.25 , NbH 0.85 and TaH 0.7 at room temperature. The results clearly show the effect of the inelastic scattering of neutrons, due to excitation of the hydrogen vibrations, and are utilized to determine the energy levels of the optical vibrations in the hydride lattices. They are 0.135 eV for TiH 1.3-2.0 , 0.165 eV for VH 0.25 , 0.150 eV for NbH 0.85 , and 0.145 eV for TaH 0.7 . It was found that there is an approximately linear relation between the energies of the optical phonons and the metal-hydrogen distances reported on various hydrides, except for palladium hydride.Keywords
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