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Second-generation fluorous chiral (salen) manganese complexes
Home
Publications
Second-generation fluorous chiral (salen) manganese complexes
Second-generation fluorous chiral (salen) manganese complexes
Marco Cavazzini
Marco Cavazzini
Amedea Manfredi
Amedea Manfredi
FM
Fernando Montanari
Fernando Montanari
SQ
Silvio Quici
Silvio Quici
Gianluca Pozzi
Gianluca Pozzi
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19 October 2000
journal article
research article
Published by
Royal Society of Chemistry (RSC)
in
Chemical Communications
No. 21
,
p.
2171-2172
https://doi.org/10.1039/b007053j
Abstract
Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50–87%) epoxidation of alkenes under fluorous biphasic conditions.
Keywords
FLUOROUS
SALEN
CHIRAL
HINDERED
STERICALLY
PERFLUOROALKYL
ENANTIOSELECTIVE
ALKENES
BIPHASIC
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