X-Ray crystal structure of bis(tetraethylammonium)di-µ-thio-[bis(phenylthio)ferrate(III)[dithiomolybdate(V)], [Et4N]2[(PhS)2FeMoS4]: a dinuclear complex with the FeMoS2core
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 361-362
- https://doi.org/10.1039/c39790000361
Abstract
An X-ray crystallographic investigation shows that the dinuclear anion [(PhS)2FeMoS4]2– consists of two edge-sharing MS4 tetrahedra (M = Mo and Fe) and the FeS2Mo planar unit.This publication has 3 references indexed in Scilit:
- The molybdenum site of nitrogenase. 2. A comparative study of molybdenum-iron proteins and the iron-molybdenum cofactor by x-ray absorption spectroscopyJournal of the American Chemical Society, 1978
- Crystal structure of tris(tetra-n-butylammonium) tri-µ-benzenethiolato-bis{tri-µ-sulphido-[µ3-sulphido-tris(benzenethiolatoiron)]molybdenum}[Bun4N]3[{(PhSFe)3MoS4}2(SPh)3]; an Fe3MoS4cubic cluster dimerJournal of the Chemical Society, Chemical Communications, 1978
- Isolation of an iron-molybdenum cofactor from nitrogenaseProceedings of the National Academy of Sciences, 1977