Individual Solvent/Solute Interactions through Social Isomerism
- 25 October 2003
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (46), 13981-13983
- https://doi.org/10.1021/ja037808e
Abstract
Reversible coencapsulation of a solute molecule and a single solvent molecule takes place in solution at ambient temperature. Two isomeric complexes are formed (social isomers), and their relative energies are assessed by NMR methods. Intermolecular interactions between 3 aromatic solutes and 15 common solvents are evaluatedKeywords
This publication has 17 references indexed in Scilit:
- Isomeric Constellations of Encapsulation Complexes Store Information on the Nanometer ScaleAngewandte Chemie International Edition, 2003
- Steric Effects and Solvent Effects in Ionic ReactionsScience, 2002
- Supermolecules by DesignAccounts of Chemical Research, 1999
- Stereochemical Relationships between Encapsulated MoleculesJournal of the American Chemical Society, 1999
- Is the Bis(-oxo)dicopper Core Capable of Hydroxylating an Arene?Angewandte Chemie International Edition, 1999
- Carceplexes and HemicarceplexesChemical Reviews, 1999
- Ring Inversion Dynamics of Encapsulated CyclohexaneJournal of the American Chemical Society, 1997
- Self-Assembling CapsulesChemical Reviews, 1997
- Molecular Torsion Balance for Weak Molecular Recognition Forces. Effects of "Tilted-T" Edge-to-Face Aromatic Interactions on Conformational Selection and Solid-State StructureJournal of the American Chemical Society, 1994
- Host-guest complexation. 56. Syntheses and properties of soluble carceplexesJournal of the American Chemical Society, 1991