Chiral Anionic Surfactants for Asymmetric Mukaiyama Aldol-Type Reaction in Water
- 1 March 2003
- journal article
- research article
- Published by SAGE Publications in Journal of Chemical Research
- Vol. 2003 (3), 153-156
- https://doi.org/10.3184/030823403103173318
Abstract
Sulfonate derivatives of chiral 1,1′-binaphthol were used as chiral anionic surfactants in asymmetric aldol-type reaction in water to give aldol adducts with moderate to good diastereo- and enantioselectivities; Ga(OTf)3 and Cu(OTf)2 were better than Sc(OTf)3 as Lewis acid catalysts.Keywords
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