Statistical mechanics of regular mixtures
Open Access
- 7 May 1951
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 206 (1086), 335-353
- https://doi.org/10.1098/rspa.1951.0074
Abstract
The approximate combinatory method devised by Fowler and Guggenheim for the treatment of superlattices is here used to derive the quasi-chemical formulae for a regular mixture regarded as a system of nearly independent pairs of neighbouring sites. The method is then applied to the same mixture regarded as a system of nearly independent triplets or quadruplets of neighbouring sites on a close-packed lattice. Quantitative results for the equilibrium properties obtained by the three approximations differ from one another only very slightly.Keywords
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