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A Short Diastereoselective Synthesis of 2,3-Disubstituted Succinates
Home
Publications
A Short Diastereoselective Synthesis of 2,3-Disubstituted Succinates
A Short Diastereoselective Synthesis of 2,3-Disubstituted Succinates
RB
R. Paul Beckett
R. Paul Beckett
MC
Michael J. Crimmin
Michael J. Crimmin
MD
Mark H. Davis
Mark H. Davis
ZS
Zoé Spavold
Zoé Spavold
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1 January 1993
journal article
letter
Published by
Georg Thieme Verlag KG
in
Synlett
Vol. 1993
(02)
,
137-138
https://doi.org/10.1055/s-1993-22378
Abstract
Alkylation of optically active succinic acid half esters provides a stereoselective route to 2,3 disubstituted succinates. Enolate formation and quenching leads to selective inversion of the stereochemistry at the newly alkylated centre.
Keywords
DIASTEREOSELECTIVE
DISUBSTITUTED
QUENCHING
NEWLY
STEREOCHEMISTRY
OPTICALLY
CENTRE
ENOLATE
ESTERS
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Cited by 30 articles