Preferred anti - 1,3- substitution by attack of organocuprates on the methane—sulfinate of (R)-(−)-3-hydroxy-3-phenylpropyne. An attractive route to chiral allenes.
- 31 December 1978
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 19 (41), 3935-3936
- https://doi.org/10.1016/s0040-4039(01)95102-0
Abstract
No abstract availableKeywords
This publication has 5 references indexed in Scilit:
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- A new synthesis of allenic hydrocarbons from tertiary 2‐propynyl sulfinates and organocopper(I) compounds. Evidence for a syn‐l,3‐substitution pattern in the steroid seriesRecueil des Travaux Chimiques des Pays-Bas, 1978
- Formation of allenes by reaction of lithium diorganocuprates on propargylic acetates - a mechanistic approachTetrahedron Letters, 1975
- Synthesis, Absolute Configuration, and Optical Purity of Chiral AllenesSynthesis, 1973
- On the formation of allenes in the steroid series II. Synthesis and structure of several 19‐nor‐17,20‐pregnadienesRecueil des Travaux Chimiques des Pays-Bas, 1971